English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

An Al-Al One-Electron π Bond

MPS-Authors

Pluta,  Christian
Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58898

Pörschke,  Klaus-Richard
Research Group Pörschke, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58723

Krüger,  Carl
Service Department Krüger (XRAY), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

Hildenbrand,  Knut
Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Pluta, C., Pörschke, K.-R., Krüger, C., & Hildenbrand, K. (1993). An Al-Al One-Electron π Bond. Angewandte Chemie International Edition, 32(3), 388-390. doi:10.1002/anie.199303881.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-289C-B
Abstract
Not a reductive rupture, but a strengthening of he result of the reduction of the dialane 1 with lithium. The salt isolated after addition of TMEDA contains the radical anion of 1, in which. as results of an X-ray structural analysis show, the Al-C bonds are distinctly longer (+ 0.06 angstrom) and the Al-Al bond considerably shorter (0.13 angstrom) than in 1 itself. These findings are in accord with results of MO calculations, which indicate a stabilization of the Al-Al bond by the additional electron.