Synthese und Reactivität von (2,6-iPr2Ph-dad)Ni(C2F4)

Schröder, Wolfgang; Bonrath, Werner; Pörschke, Klaus-Richard

doi:10.1016/0022-328X(91)86393-5

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Synthese und Reactivität von (2,6-ⁱPr₂Ph-dad)Ni(C₂F₄)

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Schröder, Wolfgang
Max-Planck-Institut für Kohlenforschung, Max Planck Society;

Bonrath, Werner
Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Pörschke, Klaus-Richard
Research Group Pörschke, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Schröder, W., Bonrath, W., & Pörschke, K.-R. (1991). Synthese und Reactivität von (2,6-ⁱPr₂Ph-dad)Ni(C₂F₄). Journal of Organometallic Chemistry, 408(2), C25-C29. doi:10.1016/0022-328X(91)86393-5.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-47CC-5

Abstract

Upon warming the reaction mixture of Ni(cdt), C₂F₄, and 2,6-ⁱPr₂Ph-dad in THF from - 78-degrees-C to room temperature the red-violet complex (2,6-ⁱPr₂Ph-dad)Ni(C₂F₄) (1) is obtained. 1 reacts with ethene already at - 78-degrees-C by coupling of the olefinic ligands with the nickel atom to form the blue nickelatetrafluoro-cyclopentane compound (2,6-ⁱPr₂Ph-dad)Ni(C₂H₄C₂F₄) (2).