Nonlinear Optical Effects on Dye Containing Molecular Sieves

Marlow, Frank; Caro, Jürgen

doi:10.1080/10587259408029728

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Nonlinear Optical Effects on Dye Containing Molecular Sieves

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Marlow, Frank
Center of Heterogeneous Catalysis , Rudower Chaussee 5, D-12484, Berlin, Germany ;
Research Group Marlow, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Marlow, F., & Caro, J. (1994). Nonlinear Optical Effects on Dye Containing Molecular Sieves. Molecular Crystals and Liquid Crystals Science and Technology Section A-Molecular Crystals and Liquid Crystals, 240(1), 175-181. doi:10.1080/10587259408029728.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-2441-2

Abstract

Composites of organic molecules and molecular sieves are promising materials for nonlinear optics. In order to achieve different NLO processes in these materials we varied the guest molecules. Paranitroaniline (PNA) and dimethylaminobenzonitrile (DMABN) were investigated in different molecular sieve hosts (AlPO-5, ZSM-5, VPI-5). These two groups of materials studied can be described by qualitatively different models: ensembles of oriented two-level or three-level systems. In contrast to molecular sieves loaded with PNA which can only mix waves of the same polarization, for the DMABN based materials the mixing of waves of different polarizations is observed.