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News from AlPO4-5: Microwave synthesis, application as medium to organize molecules for spectroscopy and nonlinear optics, material for one-dimensional membranes

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Marlow,  F.
Institute of Applied Chemistry, Rudower Chaussee 5, 12489 Berlin, Germany;
Research Group Marlow, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Kornatowski,  J.
Institut für Brennstoffchemie, RWTH (Technical University), 52074 Aachen, Germany;
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Faculty of Chemistry, N. Copernicus University, 87-100 Torun, Poland;

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Citation

Caro, J., Marlow, F., Hoffmann, K., Striebel, C., Kornatowski, J., Girnus, I., et al. (1997). News from AlPO4-5: Microwave synthesis, application as medium to organize molecules for spectroscopy and nonlinear optics, material for one-dimensional membranes. Studies in Surface Science and Catalysis, 105, 2171-2178. doi:10.1016/S0167-2991(97)80687-8.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0024-2734-A
Abstract
Synthesis of AlPO4-5, crystals of high quality results in novel applications of this molecular sieve: (i) Guest molecules become ordered in the pores of the molecular sieve crystal and allow spectroscopy on aligned molecules. (ii) Due to a specific adsorption mechanism, dipolar organic molecules become oriented by entering the pores and give nonlinear optical effects like frequency doubling (SHG). (iii) Aligned AlPO4-5 crystals in a nickel film represent a new one-dimensional membrane for molecular sieving.