Mono- and bis(ethyne)nickel(0) complexes

Pörschke, Klaus-Richard

doi:10.1021/ja00197a029

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Mono- and bis(ethyne)nickel(0) complexes

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Pörschke, Klaus-Richard
Research Group Pörschke, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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引用

Pörschke, K.-R. (1989). Mono- and bis(ethyne)nickel(0) complexes. Journal of the American Chemical Society, 111(15), 5691-5699. doi:10.1021/ja00197a029.

引用: https://hdl.handle.net/11858/00-001M-0000-0024-28A0-0

要旨

Various (ligand)nickel(0)-ethene complexes react with ethyne in ether or pentane at low temperature to afford crystalline compounds of types (R₃P)₂Ni(C₂H₂), {(RO)₃P}₂Ni(C₂H₂), (^tBuNC)₂Ni(C₂H₂), (R₃P)Ni(C₂H₂)(C₂H₄), {(R₃P)-Ni(C₂H₄)}₂(µ-C₂H₂), {(R₃P)Ni(C₂H₂)}₂(µ-C₂H₂), and (R₃P)Ni(C₂H₂)₂ (R = Me, Et, ⁱPr,Ch, Ph). The chemical and spectroscopic properties of the new complexes are reported.