English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

The Tetrakis(carbonyl)dioxoosmium(VI) Cation: trans-[OsO2(CO)4]2+

MPS-Authors
/persons/resource/persons59045

Thiel,  Walter
Research Department Thiel, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Bernhardt, E., Willner, H., Jonas, V., Thiel, W., & Aubke, F. (2000). The Tetrakis(carbonyl)dioxoosmium(VI) Cation: trans-[OsO2(CO)4]2+. Angewandte Chemie International Edition, 39(1), 168-171. doi:10.1002/(SICI)1521-3773(20000103)39:1<168:AID-ANIE168>3.0.CO;2-#.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-2B10-B
Abstract
The first carbonyl compound of a transition metal in the oxidation state +6 was obtained by reductive carbonylation of OsO4 in SbF5. Through the use of extensive IR, NMR, and UV/Vis spectroscopic studies as well as density functional calculations it was determined that the trans-[OsO2(CO)4]2+ cation adopts the octahedral structure shown in the picture with trans oxygen atoms.