English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

Temperature-dependent spectral spin diffusion in solid state deuteron magnetic resonance

MPS-Authors
/persons/resource/persons118609

Müller,  Andreas
Research Group Prof. Dr. Haeberlen, Max Planck Institute for Medical Research, Max Planck Society;

/persons/resource/persons93258

Haeberlen,  Ulrich
Research Group Prof. Dr. Haeberlen, Max Planck Institute for Medical Research, Max Planck Society;

External Resource

http://www.sciencedirect.com/science?_ob=MiamiImageURL&_cid=271350&_user=41901&_pii=0009261495013091&_check=y&_origin=article&_zone=toolbar&_coverDate=12-Jan-1996&view=c&originContentFamily=serial&wchp=dGLbVlS-zSkWA&md5=227be07236458a853dd34492813879de&pid=1-s2.0-0009261495013091-main.pdf
(Any fulltext)

http://dx.doi.org/10.1016/0009-2614(95)01309-1
(Any fulltext)

Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Müller, A., & Haeberlen, U. (1996). Temperature-dependent spectral spin diffusion in solid state deuteron magnetic resonance. Chemical Physics Letters, 248: 3-4, pp. 249-254. doi:10.1016/0009-2614(95)01309-1.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-34A7-E
Abstract
The polarization transfer from the para to the ortho/meta deuterons was investigated in a single crystal of perdeuterated biphenyl, C12D10. It is demonstrated that this process is due to spin diffusion via dipolar coupling. We found that in the range from 290 to 315 K it is strongly dependent on the temperature. The apparent activation energy of about 75 kJ/mol is the same as that of the known 180° flips of phenyl rings about the long molecular axis. As an explanation of the observed temperature dependence of the spin diffusion we discuss an exchange broadening of the relevant zero−quantum line caused by the 180° flips