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Journal Article

General and User-friendly Method for Suzuki Reactions with Aryl Chlorides

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Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Leitner,  Andreas
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Fürstner, A., & Leitner, A. (2001). General and User-friendly Method for Suzuki Reactions with Aryl Chlorides. Synlett, (2), 290-292. doi:10.1055/s-2001-10763.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-34CA-F
Abstract
Through the use of Pd(OAc)2 and the sterically hindered imidazolium salt 5 (IPr · HCl) as the pre-catalyst mixture, aryl chlorides undergo efficient cross coupling reactions with 9-R-9-BBN derivatives (R = alkyl, allyl, alkynyl, cyclopropyl) in the presence of KOMe as the base. This procedure is easily scaleable and applies to electron poor and electron rich substrates with similar ease.