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Recent Advances in Nano- and Macroscale Control of Hexagonal, Mesoporous Materials

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Linden,  Mika
Johann Wolfgang Goethe Universität, Marie Curie Str. 11, 60439, Frankfurt/M ;
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Schüth,  Ferdi
Johann Wolfgang Goethe Universität, Marie Curie Str. 11, 60439, Frankfurt/M ;
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Linden, M., Schacht, S., Schüth, F., Steel, A., & Unger, K. K. (1998). Recent Advances in Nano- and Macroscale Control of Hexagonal, Mesoporous Materials. Journal of Porous Materials, 5(3-4), 177-193. doi:10.1023/A:1009666019428.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0024-3AFD-2
Abstract
Nano- and macroscale control of siliceous MCM-41 type, hexagonal, mesoporous materials are discussed with reference to proposed mechanisms of formation and morphological manipulation. The complex interplay of surfactant silicate chemistry in the numerous synthetic strategies of MCM-41 type materials reported to date are examined. Recent advances in the growth of thin film mesoporous silicates from solid-liquid, air-liquid and liquid-liquid interfaces are reviewed. Extension into three-dimensional silicate structures is made possible through detailed control of shear flow conditions and reaction composition.