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Journal Article

Water Sorption on Mesoporous Aluminosilicate MCM-41


Schüth,  F.
Institut für Anorg.Chemie & Analyt. Chemie, Johannes Gutenberg Universität, D-55099 Mainz, Germany;
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Llewellyn, P., Schüth, F., Grillet, Y., Rouquerol, F., Rouquerol, J., & Unger, K. (1995). Water Sorption on Mesoporous Aluminosilicate MCM-41. Langmuir, 11(2), 574-577. doi:10.1021/la00002a036.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-36EF-F
Characterization of the interaction of water with the highly ordered mesoporous solid MCM-41 (pore diameter -2.5 nm) is undertaken with the aid of several techniques (adsorption gravimetry, X-ray diffraction, Fourier transform infrared spectroscopy, and controlled rate-evolved gas analysis). The relatively complex water-MCM-41 interactions are characterized by a type V isotherm indicating an initial repulsive character followed by a capillary condensation step of the adsorbate. This highlights both hydrophobic and hydrophilic properties of this potential model mesoporous adsorbent.