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The theoretical and practical limits of resolution in multiple-pulse high-resolution NMR of solids

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Haeberlen,  Ulrich
Research Group Prof. Dr. Haeberlen, Max Planck Institute for Medical Research, Max Planck Society;

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Zitation

Prigl, R., & Haeberlen, U. (1996). The theoretical and practical limits of resolution in multiple-pulse high-resolution NMR of solids. Advances in Magnetic and Optical Resonance, 19, 1-58.


Zitierlink: https://hdl.handle.net/11858/00-001M-0000-0024-37F0-1
Zusammenfassung
This chapter discusses the theoretical and practical limits of resolution in multiple-pulse (m.p.) high-resolution nuclear magnetic resonance (NMR) of solids. m.p. M.P sequences for high-resolution (NMR) in solids were introduced in 1968 by the MIT NMR group. Experimentalists working on the advance of high-resolution NMR in solids have been frustrated over many years by the apparent existence of a "magic wall" that prevented them from improving the resolution in their m.p. spectra beyond a certain limit. The purpose of this report is to explore, on the one hand, the theoretical and, on the other, the practical limitations of high-resolution solid state proton and fluorine NMR.