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Transition Metal Compound Oxide Catalysts for Lowering the Light Off-Temperature of Particles from Diesel Exhaust

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Citation

Setzer, C., Schütz, W., & Schüth, F. (1993). Transition Metal Compound Oxide Catalysts for Lowering the Light Off-Temperature of Particles from Diesel Exhaust. In L. Guczi, F. Solymosi, & P. Tétényi (Eds.), Studies in Surface Science and Catalysis: New Frontiers in Catalysis Vol 75 (pp. 2629-2632). Amsterdam: Elsevier.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-466D-5
Abstract
It has been realized that particle emissions from diesel engines are a severe environmental problem, which is difficult to solve by engine modifications alone. Even if the combustion occurs in a high excess of air, appreciable amounts of soot particles are found. Cracking processes, dehydrogenation, and polymerization play an important role in the formation of soot. To reduce soot fraction, several methods have been developed in the past, but most of them have fundamental disadvantages. Thus, a new procedure based on the catalytic burning of the soot in the exhaust gas is becoming important. This chapter describes the effect of several compound oxides. Further investigations concerning the importance of the process for the catalytic soot removal using isotope labeling and further Diffuse Reflexion Infra Red Fourier Transform (DRIFT) studies are also being carried out.