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Journal Article

Asymmetric Catalysis Using Chiral, Enantiopure Disulfonimides

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van Gemmeren,  Manuel
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Lay,  Frank
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

van Gemmeren, M., Lay, F., & List, B. (2014). Asymmetric Catalysis Using Chiral, Enantiopure Disulfonimides. Aldrichimica Acta, 47(1), 3-13.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-3E90-0
Abstract
Disulfonimides have recently emerged as powerful (pre)-catalysts, especially in Lewis acid organocatalysis. Herein, we survey the development of these catalysts, their application in asymmetric catalysis using the concept of asymmetric counteranion-directed catalysis (ACDC), and mechanistic studies that aim to elucidate the catalytic cycle and the intermediates involved.