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Journal Article

Towards High-Performance Lewis Acid Organocatalysis

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Ratjen,  Lars
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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van Gemmeren,  Manuel
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Pesciaioli,  Fabio
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Ratjen, L., van Gemmeren, M., Pesciaioli, F., & List, B. (2014). Towards High-Performance Lewis Acid Organocatalysis. Angewandte Chemie International Edition, 53(33), 8765-8769. doi:10.1002/anie.201402765.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-3E79-6
Abstract
The combination of Lewis acid organocatalysis and internal hydrogen-bond assistance was used to develop a new type of highly active disulfonimide catalyst. The increased Lewis acidity was documented by activity comparisons as well as theoretical investigations. Finally, the potential of the hydrogen-bond-assisted disulfonimide catalyst was demonstrated by its application in an enantioselective transformation.