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N-Heterocyclic carbenes can coexist with alkenes and C–H acidic sites

MPS-Authors
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Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Krause,  Helga
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Ackermann,  Lutz
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Lehmann,  Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Supplementary Material (public)

b107238b.txt
(Supplementary material), 53KB

Citation

Fürstner, A., Krause, H., Ackermann, L., & Lehmann, C. W. (2001). N-Heterocyclic carbenes can coexist with alkenes and C–H acidic sites. Chemical Communications, (21), 2240-2241. doi:10.1039/B107238B.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0024-4609-3
Abstract
The isolation of compounds 3 and 7a,b proves that a singlet carbene center can coexist with alkenes or C–H acidic sites in proximity without spontaneous annihilation.