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Preparation, structure and catalytic properties of a binuclear Pd(0) complex with bridging silylene ligands

MPS-Authors
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Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Krause,  Helga
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Lehmann,  Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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b108132b.txt
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Citation

Fürstner, A., Krause, H., & Lehmann, C. W. (2001). Preparation, structure and catalytic properties of a binuclear Pd(0) complex with bridging silylene ligands. Chemical Communications, 2001(22), 2372-2373. doi:10.1039/B108132B.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-45F1-0
Abstract
In contrast to the N-heterocyclic carbene (NHC) 1, the homologous N-heterocyclic silylene (NHS) 4 acts as a bridging ligand to Pd(0), giving rise to the dinuclear complex 5 which is catalytically active in Suzuki reactions.