[Cu2{1,4-bis[(3-methyl-2-pyridyl)amino]phthalazine-H}(N3)3] at 40K

Goeta, Andres E.; Thompson, Laurence K.; Sheppard, Christopher L.; Tandon, Santokh S.; Lehmann, Christian W.; Cosier, John; Webster, Craig; Howard, Judith A. K.

doi:10.1107/S0108270199005648

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[Cu₂{1,4-bis[(3-methyl-2-pyridyl)amino]phthalazine-H}(N₃)₃] at 40K

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Citation

Goeta, A. E., Thompson, L. K., Sheppard, C. L., Tandon, S. S., Lehmann, C. W., Cosier, J., et al. (1999). [Cu₂{1,4-bis[(3-methyl-2-pyridyl)amino]phthalazine-H}(N₃)₃] at 40K. Acta Crystallographica, Section C: Crystal Structure Communications, 55(Part 8), 1243-1246. doi:10.1107/S0108270199005648.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-6565-C

Abstract

The structure of the title compound, μ-azido-1:2κ²N¹-[μ-4-(3-methyl-2-pyridyl-2κN-amino)-1-(3-methyl-2-pyridyl-1κN-imino)-1,2-dihydrophthalazin-2-yl-1:2κ²N²:N³]-bis[(azido-κN¹)copper(II)], [Cu₂(C₂₀H₁₇N₆)(N₃)₃], (I), determined from data recorded at 40(1)K using a new open-flow He gas cryostat, is presented here as
part of an extended study program on dicopper(II) azide-bridged compounds. Each pair of Cu^II centres in (I) is equatorially bridged by a μ₂-1,1-azide, with a bridge angle of 107.2 (1)°. The dinuclear centres form tetranuclear clusters through two μ₂-1,3-azide bridges, which in turn form chains along the a axis. Two C-H...N intermolecular interactions interlink these chains
along the [110] and [11 ̅ 0] directions.