[Cu2{1,4-bis[(3-methyl-2-pyridyl)amino]phthalazine-H}(N3)3] at 40K

Goeta, Andres E.; Thompson, Laurence K.; Sheppard, Christopher L.; Tandon, Santokh S.; Lehmann, Christian W.; Cosier, John; Webster, Craig; Howard, Judith A. K.

doi:10.1107/S0108270199005648

アイテム詳細

登録内容を編集ファイル形式で保存

一時保存へ追加

タグ情報を表示リリース履歴を表示詳細要約

公開

学術論文

[Cu₂{1,4-bis[(3-methyl-2-pyridyl)amino]phthalazine-H}(N₃)₃] at 40K

MPS-Authors

There are no MPG-Authors in the publication available

External Resource

There are no locators available

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

フルテキスト (公開)

公開されているフルテキストはありません

付随資料 (公開)

There is no public supplementary material available

引用

Goeta, A. E., Thompson, L. K., Sheppard, C. L., Tandon, S. S., Lehmann, C. W., Cosier, J., Webster, C., & Howard, J. A. K. (1999). [Cu₂{1,4-bis[(3-methyl-2-pyridyl)amino]phthalazine-H}(N₃)₃] at 40K. Acta Crystallographica, Section C: Crystal Structure Communications, 55(Part 8), 1243-1246. doi:10.1107/S0108270199005648.

引用: https://hdl.handle.net/11858/00-001M-0000-0024-6565-C

要旨

The structure of the title compound, μ-azido-1:2κ²N¹-[μ-4-(3-methyl-2-pyridyl-2κN-amino)-1-(3-methyl-2-pyridyl-1κN-imino)-1,2-dihydrophthalazin-2-yl-1:2κ²N²:N³]-bis[(azido-κN¹)copper(II)], [Cu₂(C₂₀H₁₇N₆)(N₃)₃], (I), determined from data recorded at 40(1)K using a new open-flow He gas cryostat, is presented here as
part of an extended study program on dicopper(II) azide-bridged compounds. Each pair of Cu^II centres in (I) is equatorially bridged by a μ₂-1,1-azide, with a bridge angle of 107.2 (1)°. The dinuclear centres form tetranuclear clusters through two μ₂-1,3-azide bridges, which in turn form chains along the a axis. Two C-H...N intermolecular interactions interlink these chains
along the [110] and [11 ̅ 0] directions.