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Towards Biological Supramolecular Chemistry: A Variety of Pocket-Templated Metal Oxide Cluster Nucleations in the Cavity of a Mo/W-Storage Protein

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Demmer,  Ulrike
Department of Molecular Membrane Biology, Max Planck Institute of Biophysics, Max Planck Society;

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Warkentin,  Eberhard
Department of Molecular Membrane Biology, Max Planck Institute of Biophysics, Max Planck Society;

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Ermler,  Ulrich
Department of Molecular Membrane Biology, Max Planck Institute of Biophysics, Max Planck Society;

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Citation

Schemberg, J., Schneider, K., Demmer, U., Warkentin, E., Müller, A., & Ermler, U. (2007). Towards Biological Supramolecular Chemistry: A Variety of Pocket-Templated Metal Oxide Cluster Nucleations in the Cavity of a Mo/W-Storage Protein. Angewandte Chemie, International Edition in English, 46(14), 2408-2413. doi:10.1002/anie.200604858.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0024-D8DF-D
Abstract
Create and protect: The cavity shell of a molybdenum/tungsten‐storage protein acts as a polytopic host for several types of polyoxotungstate guests, which occur as individual clusters (one shown: yellow W, red O, ribbons protein) that are noncovalently or weakly bonded to the host. The formation of the guests is templated by the specific functionalities of the protein pockets.