Low temperature neutron and X-ray diffraction study of 
imino(triphenyl)phosphorane

Davidson, Matthew G.; Goeta, Andrés E.; Howard, Judith A. K.; Lehmann, Christian W.; McIntyre, Garry M.; Price, Richard D.

doi:10.1016/S0022-328X(97)00551-2

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Low temperature neutron and X-ray diffraction study of imino(triphenyl)phosphorane

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Davidson, M. G., Goeta, A. E., Howard, J. A. K., Lehmann, C. W., McIntyre, G. M., & Price, R. D. (1998). Low temperature neutron and X-ray diffraction study of imino(triphenyl)phosphorane. Journal of Organometallic Chemistry, 550(1-2), 449-452. doi:10.1016/S0022-328X(97)00551-2.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-76B5-D

Abstract

The structure of imino(triphenyl)phosphorane, Ph₃PNH 1 has been determined by low-temperature X-ray and neutron diffraction. This dual study is the first such for an iminophosphorane. From the neutron diffraction data, the P–N bond length is 1.582(2) Å and the P–N–H angle is 115.0(2)°.