Gold(III) compounds containing a chelating, dicarbanionic ligand derived from 
4,4′-di-tert-butylbiphenyl

David, B.; Monkowius, U.; Rust, J.; Lehmann, C. W.; Hyzak, L.; Mohr, F.

doi:10.1039/C4DT00778F

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Gold(III) compounds containing a chelating, dicarbanionic ligand derived from 4,4′-di-tert-butylbiphenyl

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Rust, J.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Lehmann, C. W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

Mohr, F.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

David, B., Monkowius, U., Rust, J., Lehmann, C. W., Hyzak, L., & Mohr, F. (2014). Gold(III) compounds containing a chelating, dicarbanionic ligand derived from 4,4′-di-tert-butylbiphenyl. Dalton Transactions, 43(28), 11059-11066. doi:10.1039/C4DT00778F.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-BFA2-8

Abstract

An oligomeric gold(III) compound containing dicarbanionic chelating 4,4′-di-tert-butylbiphenyl was prepared via transmetallation using the corresponding organotin(IV) compound. The reactivity of the chloro-bridged oligomer with various species including neutral N-, P-, and C-donor ligands as well as monoanionic S- and Se-ligands was investigated. Some of the products were characterised by X-ray crystallography. The photophysical properties of two derivatives were studied.