English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Carbenes Stabilized by Ylides: Pushing the Limits

MPS-Authors
/persons/resource/persons58380

Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58392

Alcarazo,  Manuel
Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58907

Radkowski,  Karin
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58744

Lehmann,  Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Ressource
No external resources are shared
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)

z803200_s.pdf
(Supplementary material), 202KB

Citation

Fürstner, A., Alcarazo, M., Radkowski, K., & Lehmann, C. W. (2008). Carbenes Stabilized by Ylides: Pushing the Limits. Angewandte Chemie International Edition, 47(43), 8302-8306. doi:10.1002/anie.200803200.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0024-C2D0-7
Abstract
Being neighborly: The concept of placing two reactive intermediates next to each other to gain stability is borne out in amino(ylide)carbenes (AYCs). Different kinds of ylides stabilize an adjacent singlet carbene by donation of electron density from the ylidic carbon atom into the empty p orbital to give AYCs of various structural formats (see picture) that are distinguished by their exceptionally strong σ-donor qualities.