On the Nature of the Reactive Intermediates in Gold-Catalyzed 
Cycloisomerization Reactions

Fürstner, Alois; Morency, Louis

doi:10.1002/anie.200800934

アイテム詳細

登録内容を編集ファイル形式で保存

一時保存へ追加

タグ情報を表示リリース履歴を表示詳細要約

公開

学術論文

On the Nature of the Reactive Intermediates in Gold-Catalyzed Cycloisomerization Reactions

MPS-Authors

/persons/resource/persons58380

Fürstner, Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58829

Morency, Louis
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource

There are no locators available

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

フルテキスト (公開)

公開されているフルテキストはありません

付随資料 (公開)

anie_200800934_sm_miscellaneous_information.pdf
(付録資料), 124KB

引用

Fürstner, A., & Morency, L. (2008). On the Nature of the Reactive Intermediates in Gold-Catalyzed Cycloisomerization Reactions. Angewandte Chemie International Edition, 47(27), 5030-5033. doi:10.1002/anie.200800934.

引用: https://hdl.handle.net/11858/00-001M-0000-0024-B3CA-E

要旨

A gold rush: The Stork–Eschenmoser postulate explaining the course and stereoselectivity of cationic polyene cyclization reactions also holds true for cycloisomerization reactions catalyzed by gold. This result suggests that the pertinent intermediates (see scheme) are more adequately described as gold- stabilized carbocations rather than as gold carbenes. E=COOMe, L=neutral ligand.