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Structural Rigidity and Luminescence of Chiral Lanthanide Tetraamide Complexes Based on 1,4,7,10-Tetraazacyclododecane

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Citation

Dickins, R. S., Howard, J. A. K., Lehmann, C. W., Moloney, J., Parker, D., & Peacock, R. D. (1997). Structural Rigidity and Luminescence of Chiral Lanthanide Tetraamide Complexes Based on 1,4,7,10-Tetraazacyclododecane. Angewandte Chemie International Edition, 36(5), 521-523. doi:10.1002/anie.199705211.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-BF4E-6
Abstract
The enantiopure europium and terbium complexes of the macrocyclic ligand 1 are conformationally rigid in solution. The cationic terbium complex gives rise to an intense circularly polarized emission, which offers much promise for its use as a chiral probe.