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Elemental fluorine. Part 6. Fluorination of cyclic 1,3-diketones and related compounds

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Lehmann,  C.W.
Department of Chemistry, BNFL Fluorochemicals Ltd and Chemical Crystallography Unit, University of Durham, Science Laboratories, South Road, Durham DHI 3LE, UK ;
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Chambers, R., Hutchinson, J., Batsanov, A., Lehmann, C., & Naumov, D. (1996). Elemental fluorine. Part 6. Fluorination of cyclic 1,3-diketones and related compounds. Journal of the Chemical Society, Perkin Transactions 1, (18), 2271-2275. doi:10.1039/p19960002271.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0024-BF43-B
Abstract
Direct fluorination of cyclic 1,3-diones gives 2-mono- and 2,2-di-fluorinated products. The monofluorinated compounds crystallise in their enol forms and the difluorinated compounds form stable monohydrates whose crystal structures have been elucidated, Direct fluorination of phloroglucinol double dagger in formic acid yields 1,1,3,3,5,5-hexafluoro-2,2,4,4,6,6-hexahydroxtcyclohexane.