English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Elemental fluorine. Part 6. Fluorination of cyclic 1,3-diketones and related compounds

MPS-Authors
There are no MPG-Authors available
External Ressource
No external resources are shared
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Chambers, R. D., Hutchinson, J., Batsanov, A. S., Lehmann, C. W., & Naumov, D. Y. (1996). Elemental fluorine. Part 6. Fluorination of cyclic 1,3-diketones and related compounds. Journal of the Chemical Society, Perkin Transactions 1, (18), 2271-2275. doi:10.1039/p19960002271.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0024-BF43-B
Abstract
Direct fluorination of cyclic 1,3-diones gives 2-mono- and 2,2-di-fluorinated products. The monofluorinated compounds crystallise in their enol forms and the difluorinated compounds form stable monohydrates whose crystal structures have been elucidated. Direct fluorination of phloroglucinol 1 in formic acid yields l,1,3,3,5,5-hexafluoro-2,2,4,4,6,6-hexahydroxycyclohexane.