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Novel bonding modes in metallo–dithiadiazolyl complexes: preparation and crystal structures of [Pt(SNCPhNS-S,S)(PPh3)2]·MeCN and [Pt3(µ-SNCPhNS-S,S)2(PPh3)4·2PhMe

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Banister, A. J., Gorell, I. B., Lawrence, S. E., Lehmann, C. W., May, I., Tate, G., et al. (1994). Novel bonding modes in metallo–dithiadiazolyl complexes: preparation and crystal structures of [Pt(SNCPhNS-S,S)(PPh3)2]·MeCN and [Pt3(µ-SNCPhNS-S,S)2(PPh3)4·2PhMe. Journal of the Chemical Society, Chemical Communications, (15), 1779-1780. doi:10.1039/c39940001779.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0024-BF3A-1
Abstract
Reaction of [Pt(PPh3)3] with (Ph[graphic omitted])2 in MeCN leads to [Pt(SNCPhNS-S-S,S)(PPh3)2]·MeCN, which decomposes in toluene to give a novel trimetallic species, [Pt3(µ-SNCPhNS-S,S)2(PPh3)4]; the structures of both compounds are reported.