Novel bonding modes in metallo–dithiadiazolyl complexes: preparation and 
crystal structures of [Pt(SNCPhNS-S,S)(PPh3)2]·MeCN and [Pt3(µ-SNCPhNS-S,S)2(PPh
3)4·2PhMe

Banister, A.J.; Gorell, I.B.; Lawrence, S.E.; Lehmann, C.W.; May, I.; Tate, G.; Blake, A.J.; Rawson, J.M.

doi:10.1039/c39940001779

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Novel bonding modes in metallo–dithiadiazolyl complexes: preparation and crystal structures of [Pt(SNCPhNS-S,S)(PPh₃)₂]·MeCN and [Pt₃(µ-SNCPhNS-S,S)₂(PPh₃)₄·2PhMe

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Lehmann, C.W.
Department of Chemistry, The University of Durham, South Road, Durham, UK OH7 3LE ;
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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引用

Banister, A., Gorell, I., Lawrence, S., Lehmann, C., May, I., Tate, G., Blake, A., & Rawson, J. (1994). Novel bonding modes in metallo–dithiadiazolyl complexes: preparation and crystal structures of [Pt(SNCPhNS-S,S)(PPh₃)₂]·MeCN and [Pt₃(µ-SNCPhNS-S,S)₂(PPh₃)₄·2PhMe. Journal of the Chemical Society, Chemical Communications, (15), 1779-1780. doi:10.1039/c39940001779.

引用: https://hdl.handle.net/11858/00-001M-0000-0024-BF3A-1

要旨

Reaction of [Pt(PPh₃)₃] with (Ph[graphic omitted])₂ in MeCN leads to [Pt(SNCPhNS-S-S,S)(PPh₃)₂]·MeCN, which decomposes in toluene to give a novel trimetallic species, [Pt₃(µ-SNCPhNS-S,S)₂(PPh₃)₄]; the structures of both compounds are reported.