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Journal Article

Novel cycloadditions of isoquinoline Reissert salts

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Bridge, A. W., Hursthouse, M., Lehmann, C. W., Lythgoe, D. J., & Newton, C. G. (1993). Novel cycloadditions of isoquinoline Reissert salts. Journal of the Chemical Society, Perkin Transactions 1, (16), 1839-1847. doi:10.1039/p19930001839.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0024-BF2F-C
Abstract
Isoquinoline Reissert salts 5 partake in novel cycloadditions with acetylenic aldehydes 11 giving novel oxazoles 14 which have been characterised by X-ray crystallography. In contrast, closely related phthalazine Reissert salts 6 and phenanthridine Reissert salts 15 react by an alternative pathway giving pyrrolo[2,1-a]phthalazines 12 and pyrrolo[1,2-f]phenanthridines 16 respectively.