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Stability of nanostructured iridium oxide electrocatalysts during oxygen evolution reaction in acidic environment

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Cherevko,  Serhiy
Electrocatalysis, Interface Chemistry and Surface Engineering, Max-Planck-Institut für Eisenforschung GmbH, Max Planck Society;

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Žeradjanin,  Aleksandar R.
Electrocatalysis, Interface Chemistry and Surface Engineering, Max-Planck-Institut für Eisenforschung GmbH, Max Planck Society;

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Mayrhofer,  Karl J. J.
Electrocatalysis, Interface Chemistry and Surface Engineering, Max-Planck-Institut für Eisenforschung GmbH, Max Planck Society;

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Citation

Cherevko, S., Reier, T., Žeradjanin, A. R., Pawolek, Z., Strasser, P., & Mayrhofer, K. J. J. (2014). Stability of nanostructured iridium oxide electrocatalysts during oxygen evolution reaction in acidic environment. Electrochemistry Communucations, 48, 81-85. doi:10.1016/j.elecom.2014.08.027.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-C9B0-A
Abstract
The electrochemical stability of thermally prepared Ir oxide films is investigated using a scanning flow cell (SFC)-inductively coupled plasma mass-spectrometer (ICP-MS) setup under transient and stationary potential and/or current conditions. Time-resolved dissolution rates provide important insights into critical conditions for material breakdown and a fully quantitative in-situ assessment of the electrochemical stability during oxygen evolution reaction (OER) conditions. In particular, the results demonstrate that stability and OER activity of the IrOx catalysts strongly depend on the chemical and structural nature of Ir oxide species and their synthesis conditions. (C) 2014 The Authors. Published by Elsevier B.V.