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Unusual Structure and Reactivity of a Homoleptic "Super-Ate" Complex of Iron: Implications for Grignard Additions, Cross-Coupling Reactions, and the Kharasch Deconjugation

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Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Krause,  Helga
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Lehmann,  Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Fürstner, A., Krause, H., & Lehmann, C. W. (2006). Unusual Structure and Reactivity of a Homoleptic "Super-Ate" Complex of Iron: Implications for Grignard Additions, Cross-Coupling Reactions, and the Kharasch Deconjugation. Angewandte Chemie International Edition, 45(3), 440-444. doi:10.1002/anie.200502859.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0025-AE45-2
Abstract
The additional molecule of methyllithium present in [(Me4Fe)(MeLi)][Li(OEt2)]2 (1), the first structurally characterized ate complex of FeII bearing only alkyl substituents without any further stabilizing ligands (see picture: Fe: magenta; Li: cyan; O: red; C and H: gray), is a particularly remarkable structural feature and contributes to the fascinating reactivity profile of 1 in the title reactions.