Practical and General Palladium-Catalyzed Synthesis of Ketones from Internal 
Olefins

Morandi, Bill; Wickens, Zachary K.; Grubbs, Robert H.

doi:10.1002/anie.201209541

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Practical and General Palladium-Catalyzed Synthesis of Ketones from Internal Olefins

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Morandi, Bill
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125 (USA);
Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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引用

Morandi, B., Wickens, Z. K., & Grubbs, R. H. (2013). Practical and General Palladium-Catalyzed Synthesis of Ketones from Internal Olefins. Angewandte Chemie International Edition, 52(10), 2944-2948. doi:10.1002/anie.201209541.

引用: https://hdl.handle.net/11858/00-001M-0000-0025-BA88-B

要旨

Make it simple! A convenient and general palladium-catalyzed oxidation of internal olefins to ketones is reported. The transformation occurs at room temperature and shows wide substrate scope. Applications to the oxidation of seed-oil derivatives and a bioactive natural product are described, as well as intriguing mechanistic features.