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On the faradaic selectivity and the role of surface inhomogeneity during the chlorine evolution reaction on ternary Ti–Ru–Ir mixed metal oxide electrocatalysts

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Žeradjanin,  Aleksandar R.
Analytical Chemistry, Center for Electrochemical Sciences-CES, Ruhr-Universität Bochum, Universitätsstr. 150, D-44780 Bochum, Germany;
Electrocatalysis, Interface Chemistry and Surface Engineering, Max-Planck-Institut für Eisenforschung GmbH, Max Planck Society;

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Strasser,  Peter
Department of Chemistry, Technical University Berlin, Straße des 17., Berlin, Germany ;
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Žeradjanin, A. R., Menzel, N., Schuhmann, W., & Strasser, P. (2014). On the faradaic selectivity and the role of surface inhomogeneity during the chlorine evolution reaction on ternary Ti–Ru–Ir mixed metal oxide electrocatalysts. Physical Chemistry Chemical Physics, 16(27), 13741-13747. doi:10.1039/c4cp00896k.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0026-A0E4-E
Abstract
The faradaic selectivity of the chlorine evolution reaction (CER) and oxygen evolution reaction (OER) on the industrially important Ti-Ru-Ir mixed metal oxide is discussed. Absolute evolution rates as well as volume fractions of Cl-2 and O-2 were quantified using differential electrochemical mass spectrometry (DEMS), while the catalyst surface redox behavior was analyzed using cyclic voltammetry. The spatial inhomogeneity of the surface catalytic reaction rate was probed using Scanning Electrochemical Microscopy (SECM). Although the nature of the competition between electrochemical discharging of chloride ions and water molecules remains elusive on a molecular scale, new insights into the spatial reactivity distribution of the CER and OER were obtained. Oxidation of water is the initial step in corrosion and concomitant deactivation of the oxide electrodes; however, at the same time the nature of interaction between the oxide surface and water is used as a rational indicator of selectivity and catalytic activity. An experimental procedure was established that would allow the study of selectivity of a variety of different catalyst materials using polycrystalline electrode surfaces.