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Enantioselective Cobalt-Catalyzed Preparation of Trifluoromethyl-Substituted Cyclopropanes

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Morandi,  Bill
Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Laboratorium für Organische Chemie, ETH Zürich, CH-8093 Zürich, Switzerland;

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Citation

Morandi, B., Mariampillai, B., & Carreira, E. M. (2011). Enantioselective Cobalt-Catalyzed Preparation of Trifluoromethyl-Substituted Cyclopropanes. Angewandte Chemie International Edition, 50(5), 1101-1104. doi:10.1002/anie.201004269.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0026-A1F4-2
Abstract
Easy access on water: A cobalt-catalyzed asymmetric preparation of trifluoromethylcyclopropanes has been developed that yields high enantioselectivities with a broad range of styrene substrates (see scheme). The reaction presents a new access to enantioenriched CF3-containing building blocks.