English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

Butadiene from acetylene–ethylene cross-metathesis

MPS-Authors
/persons/resource/persons132899

Trotus,  Ioan-Teodor
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons132845

Zimmermann,  Tobias
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons146595

Duyckaerts,  Nicolas
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons132849

Geboers,  Jan
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58985

Schüth,  Ferdi
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Trotus, I.-T., Zimmermann, T., Duyckaerts, N., Geboers, J., & Schüth, F. (2015). Butadiene from acetylene–ethylene cross-metathesis. Chemical Communications, 51(33), 7124-7127. doi:10.1039/C5CC00853K.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0026-BACF-D
Abstract
Acetylene to butadiene direct synthesis, via enyne cross-metathesis, is demonstrated with commercial ruthenium carbene catalysts. Using excess of ethylene, yields greater than 50% are obtained. High activity is observed in the first minute of the reaction (TOF > 800 h−1 based on butadiene). Catalyst reusability and poisoning are discussed.