Towards quantum mechanical description of the unconventional mass-dependent 
isotope effect in ozone: Resonance recombination in the strong collision 
approximation

Grebenshchikov, Sergej Yuri; Schinke, Reinhard

doi:10.1063/1.3253994

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Towards quantum mechanical description of the unconventional mass-dependent isotope effect in ozone: Resonance recombination in the strong collision approximation

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Grebenshchikov, Sergej Yuri
Max Planck Society;

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Schinke, Reinhard
Max Planck Institute for Dynamics and Self-Organization, Max Planck Society;

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Citation

Grebenshchikov, S. Y., & Schinke, R. (2009). Towards quantum mechanical description of the unconventional mass-dependent isotope effect in ozone: Resonance recombination in the strong collision approximation. Journal of Chemical Physics, 131, 181103-1-181103-4. doi:10.1063/1.3253994.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0029-12A7-3

Abstract

The dependence of ozone recombination rate on the masses of oxygen isotopes is examined in the strong collision approximation by means of quantum mechanical calculations of resonance spectra of several rotating isotopomers. The measured ∆ ZPE effect and its temperature dependence can be reconstructed from partial widths of narrow nonoverlapping resonances. The effect is attributed to substantial contributions of highly rotationally excited states to recombination.