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Primary ammonium/tertiary amine-mediated controlled ring opening polymerisation of amino acid N-carboxyanhydrides

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Vacogne,  Charlotte D.
Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Citation

Vacogne, C. D., & Schlaad, H. (2015). Primary ammonium/tertiary amine-mediated controlled ring opening polymerisation of amino acid N-carboxyanhydrides. Chemical Communications, 51(86), 15645-15648. doi:10.1039/C5CC06905J.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0028-79E1-9
Abstract
Stable commercial primary ammonium chlorides were combined with tertiary amines to initiate the controlled ring opening polymerisation of amino acid N-carboxyanhydrides to yield polypeptides with defined end group structure, predetermined molar mass and narrow molar mass distribution.