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Conference Paper

Elucidating Charge Delocalization in the High-Spin State of aqueous FeII Spin-Crossover Compounds via Time-Resolved Spectroscopy in the X-ray Water Window

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epjconf_up2012_05037.pdf
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Huse, N., Van Kuiken, B. E., Cho, H., Strader, M. L., Kim, T. K., Khalil, M., et al. (2013). Elucidating Charge Delocalization in the High-Spin State of aqueous FeII Spin-Crossover Compounds via Time-Resolved Spectroscopy in the X-ray Water Window. EPJ Web of Conferences, 41: 05037. doi:10.1051/epjconf/20134105037.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0029-1A1A-7
Abstract
We report the first time-resolved spectroscopy of aqueous solution in the Xray water window. Nitrogen K-edge spectra, combined with ab initio calculations, reveal distinct charge delocalization, shedding light on the origins of ultrafast spin crossover.