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Disulfonimide-Catalyzed Asymmetric Synthesis of δ-Amino-β-Keto Esters

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Wang,  Qinggang
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Wang, Q., & List, B. (2015). Disulfonimide-Catalyzed Asymmetric Synthesis of δ-Amino-β-Keto Esters. Synlett, 26(6), 807-809. doi:10.1055/s-0034-1379999.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0029-75DF-9
Abstract
A chiral disulfonimide-catalyzed asymmetric synthesis of δ-amino-β-keto esters via a vinylogous Mukaiyama–Mannich reaction of the Chan diene with N-Boc imines has been developed. The desired products were obtained in good to excellent yields and enantioselectivities.