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Borderline particles : approaching the limit between colloidal stability and instability during heterophase polymerization

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Yu,  Ran
Klaus Tauer, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Peh,  Eddie
Klaus Tauer, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Mavliutova,  Liliia
Klaus Tauer, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Weber,  Nancy
Klaus Tauer, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Tauer,  Klaus
Klaus Tauer, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Citation

Yu, R., Peh, E., Mavliutova, L., Weber, N., & Tauer, K. (2016). Borderline particles: approaching the limit between colloidal stability and instability during heterophase polymerization. Macromolecular Chemistry and Physics, 217(7), 901-911. doi:10.1002/macp.201500441.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0029-AA75-E
Abstract
Multiple suspension particles — a new morphology of polymer particles — are generated on the verge of colloidal stability in the course of redox-initiated aqueous heterophase copolymerization. These particles consist of block copolymers which are arranged in the form of a micrometer-sized poly(N-isopropylacrylamide) physical network as scaffold containing nanometer-sized particles of hydrophobic polymers covalently attached.