Chiral Analysis Using Broadband Rotational Spectroscopy

Shubert, V. Alvin; Schmitz, David; Pérez, Cristóbal; Medcraft, Chris; Krin, Anna; Domingos, Sérgio R.; Patterson, David; Schnell, Melanie

doi:10.1021/acs.jpclett.5b02443

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Chiral Analysis Using Broadband Rotational Spectroscopy

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/persons/resource/persons140390

Shubert, V. Alvin
Structure and Dynamics of Cold and Controlled Molecules, Independent Research Groups, Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society;
Center for Free-Electron Laser Science, Luruper Chaussee 149, D-22761 Hamburg, Germany;

/persons/resource/persons140388

Schmitz, David
Structure and Dynamics of Cold and Controlled Molecules, Independent Research Groups, Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society;
Center for Free-Electron Laser Science, Luruper Chaussee 149, D-22761 Hamburg, Germany;

/persons/resource/persons188136

Pérez, Cristóbal
Structure and Dynamics of Cold and Controlled Molecules, Independent Research Groups, Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society;
Center for Free-Electron Laser Science, Luruper Chaussee 149, D-22761 Hamburg, Germany;
The Hamburg Centre for Ultrafast Imaging, Universität Hamburg, Luruper Chaussee 149, D-22761 Hamburg, Germany;

/persons/resource/persons140396

Medcraft, Chris
Structure and Dynamics of Cold and Controlled Molecules, Independent Research Groups, Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society;
Center for Free-Electron Laser Science, Luruper Chaussee 149, D-22761 Hamburg, Germany;

/persons/resource/persons146333

Krin, Anna
Structure and Dynamics of Cold and Controlled Molecules, Independent Research Groups, Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society;
Center for Free-Electron Laser Science, Luruper Chaussee 149, D-22761 Hamburg, Germany;

/persons/resource/persons188933

Domingos, Sérgio R.
Structure and Dynamics of Cold and Controlled Molecules, Independent Research Groups, Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society;
Center for Free-Electron Laser Science, Luruper Chaussee 149, D-22761 Hamburg, Germany;
The Hamburg Centre for Ultrafast Imaging, Universität Hamburg, Luruper Chaussee 149, D-22761 Hamburg, Germany;

/persons/resource/persons22077

Schnell, Melanie
Structure and Dynamics of Cold and Controlled Molecules, Independent Research Groups, Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society;
Center for Free-Electron Laser Science, Luruper Chaussee 149, D-22761 Hamburg, Germany;
The Hamburg Centre for Ultrafast Imaging, Universität Hamburg, Luruper Chaussee 149, D-22761 Hamburg, Germany;

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http://dx.doi.org/10.1021/acs.jpclett.5b02443
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Citation

Shubert, V. A., Schmitz, D., Pérez, C., Medcraft, C., Krin, A., Domingos, S. R., et al. (2016). Chiral Analysis Using Broadband Rotational Spectroscopy. The Journal of Physical Chemistry Letters, 7(2), 341-350. doi:10.1021/acs.jpclett.5b02443.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0029-AA7C-F

Abstract

Broadband microwave spectroscopy is a proven tool to precisely determine molecular properties of gas-phase molecules. Recent developments make it applicable to investigate chiral molecules. Enantiomers can be differentiated, and the enantiomeric excess and, indirectly, the absolute configuration can be determined in a molecule-selective manner. The resonant character and high resolution of rotational spectroscopy provide a unique mixture compatibility. Future directions, such as extending the technique to chemical analysis, are discussed.