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Synthesis of polysarcosine from air and moisture stable N-phenoxycarbonyl-N-methylglycine assisted by tertiary amine base

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Doriti,  Afroditi
Davide Esposito, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Brosnan,  Sarah M.
Helmut Schlaad, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Citation

Doriti, A., Brosnan, S. M., Weidner, S. M., & Schlaad, H. (2016). Synthesis of polysarcosine from air and moisture stable N-phenoxycarbonyl-N-methylglycine assisted by tertiary amine base. Polymer Chemistry, 7(18), 3067-3070. doi:10.1039/C6PY00221H.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002A-33D8-4
Abstract
Polysarcosine (Mn = 3650-20 000 g mol-1, D [similar] 1.1) was synthesized from the air and moisture stable N-phenoxycarbonyl-N-methylglycine. Polymerization was achieved by in situ transformation of the urethane precursor into the corresponding N-methylglycine-N-carboxyanhydride, when in the presence of a non-nucleophilic tertiary amine base and a primary amine initiator.