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β-Ag3RuO4, a Ruthenate(V) Featuring Spin Tetramers on a Two-Dimensional Trigonal Lattice

MPG-Autoren
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Prasad,  Beluvalli E.
Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Kazin,  Pavel
Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Komarek,  A. C.
Alexander Komarek, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Felser,  Claudia
Claudia Felser, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Jansen,  Martin
Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Zitation

Prasad, B. E., Kazin, P., Komarek, A. C., Felser, C., & Jansen, M. (2016). β-Ag3RuO4, a Ruthenate(V) Featuring Spin Tetramers on a Two-Dimensional Trigonal Lattice. Angewandte Chemie International Edition in English, 55(14), 4467-4471. doi:10.1002/anie.201510576.


Zitierlink: http://hdl.handle.net/11858/00-001M-0000-002A-4FD5-7
Zusammenfassung
Open-shell solids exhibit a plethora of intriguing physical phenomena that arise from a complex interplay of charge, spin, orbital, and spin-state degrees of freedom. Comprehending these phenomena is an indispensable prerequisite for developing improved functional materials. This type of understanding can be achieved, on the one hand, by experimental and theoretical investigations into known systems, or by synthesizing new solids displaying unprecedented structural and/or electronic features. -Ag3RuO4 may serve as such a model system because it possesses a remarkable anionic structure, consisting of tetrameric polyoxoanions (Ru4O16)(12-), and is an embedded fragment of a 2D trigonal MO2 lattice. The notorious frustration of antiferromagnetic (AF) exchange couplings on such lattices is thus lifted, and instead strong AF occurs within the oligomeric anion, where only one exchange path remains frustrated among the relevant six. The strong magnetic anisotropy of the [Ru4O16](12-) ion, and the effectively orbital nature of its net magnetic moment, implies that this anion may reveal the properties of a single-molecule magnet if well-diluted in a diamagnetic matrix.