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Condensed-Phase, Halogen-Bonded CF3I and C2F5I Adducts for Perfluoroalkylation Reactions

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Citation

Sladojevich, F., McNeill, E., Börgel, J., Zheng, S.-L., & Ritter, T. (2015). Condensed-Phase, Halogen-Bonded CF3I and C2F5I Adducts for Perfluoroalkylation Reactions. Angewandte Chemie International Edition in English, 54(12), 3712-3716. doi:DOI: 10.1002/anie.201410954.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002B-784C-A
Abstract
A family of practical, liquid trifluoromethylation and pentafluoroethylation reagents is described. We show how halogen bonding can be used to obtain easily handled liquid reagents from gaseous CF3I and CF3CF2I. The synthetic utility of the new reagents is exemplified by a novel direct arene trifluoromethylation reaction as well as adaptations of other perfluoroalkylation reactions.