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New electron donor-acceptor compounds, 51. [3](N,N′)-1,8;4,5-naphthalenetetracarboxdiimido-[3](2,7)pyrenophane and its [4,4]cyclophane homologue

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Staab,  Heinz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Zhang,  De-Quing
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Krieger,  Claus
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Citation

Staab, H. A., Zhang, D.-Q., & Krieger, C. (1997). New electron donor-acceptor compounds, 51. [3](N,N′)-1,8;4,5-naphthalenetetracarboxdiimido-[3](2,7)pyrenophane and its [4,4]cyclophane homologue. Liebigs Annalen der Chemie, 1997(7), 1551-1556. doi:10.1002/jlac.199719970735.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002B-2336-9
Abstract
Electron donor-acceptor cyclophanes 1 and 2, consisting of pyrene as the donor component and 1,8;4,5-naphthalenete-tracarboxdiimide as the acceptor component fixed by methylene chains in parallel face-to-face orientations, have been synthesized. The structures, based on an X-ray analysis of 1 and on spectroscopic properties, are discussed with reference to intramolecular charge-transfer interactions and are compared to those of the related excimer models [3.3]- and [4.4]pyrenophanes 3 and 4.