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The plastic crystalline A15 phase of dimethylaminoalane, [N(CH3)2–AlH2]3

MPS-Authors
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Ley,  M. B.
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Bernert,  T.
Research Group Weidenthaler, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Goddard,  R.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Farès,  C.
Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Weidenthaler,  C.
Research Group Weidenthaler, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Felderhoff,  M.
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Ley, M. B., Bernert, T., Ruiz-Fuertes, J., Goddard, R., Farès, C., Weidenthaler, C., et al. (2016). The plastic crystalline A15 phase of dimethylaminoalane, [N(CH3)2–AlH2]3. Chemical Communications, 52(78), 11649-11652. doi:10.1039/C6CC06166D.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002B-787F-9
Abstract
A plastic crystalline phase of dimethylaminoalane has been discovered at T > 332 K. The phase transitions solid – plastic phase – liquid are fully reversible. The plastic crystalline phase exhibits a cubic unit cell, space group Pm3̅ n, in which the dimethylaminoalane molecules rotate and adopt a structural arrangement reminiscent of the A15 phase.