English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

The plastic crystalline A15 phase of dimethylaminoalane, [N(CH3)2–AlH2]3

MPS-Authors
/persons/resource/persons183469

Ley,  M. B.
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons181104

Bernert,  T.
Research Group Weidenthaler, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58578

Goddard,  R.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58537

Farès,  C.
Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons59100

Weidenthaler,  C.
Research Group Weidenthaler, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58541

Felderhoff,  M.
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Ley, M. B., Bernert, T., Ruiz-Fuertes, J., Goddard, R., Farès, C., Weidenthaler, C., et al. (2016). The plastic crystalline A15 phase of dimethylaminoalane, [N(CH3)2–AlH2]3. Chemical Communications, 52(78), 11649-11652. doi:10.1039/C6CC06166D.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002B-787F-9
Abstract
A plastic crystalline phase of dimethylaminoalane has been discovered at T > 332 K. The phase transitions solid – plastic phase – liquid are fully reversible. The plastic crystalline phase exhibits a cubic unit cell, space group Pm3̅ n, in which the dimethylaminoalane molecules rotate and adopt a structural arrangement reminiscent of the A15 phase.