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Journal Article

Temperature and pressure dependence of the reaction S + CS (+M) → CS2 (+M).


Troe,  J.
Emeritus Group of Spectroscopy and Photochemical Kinetics, MPI for Biophysical Chemistry, Max Planck Society;

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Glarborg, P., Marshall, P., & Troe, J. (2015). Temperature and pressure dependence of the reaction S + CS (+M) → CS2 (+M). Journal of Physical Chemistry A, 119(28), 7277-7281. doi:10.1021/jp5121492.

Cite as: https://hdl.handle.net/11858/00-001M-0000-002B-76C6-C
Experimental data for the unimolecular decomposition of CS2 from the literature are analyzed by unimolecular rate theory with the goal of obtaining rate constants for the reverse reaction S + CS (+M) → CS2 (+M) over wide temperature and pressure ranges. The results constitute an important input for the kinetic modeling of CS2 oxidation. CS2 dissociation proceeds as a spin-forbidden process whose detailed properties are still not well understood. The role of the singlet-triplet transition involved is discussed.