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Journal Article

Synergistic Interaction within Bifunctional Ruthenium Nanoparticle/SILP Catalysts for the Selective Hydrodeoxygenation of Phenols

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Leitner,  Walter
Institut für Technische und Makromolekulare Chemie (ITMC), RWTH Aachen University, Worringerweg 1, 52074 Aachen (Germany);
Research Group Leitner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Luska, K. L., Migowski, P., El Sayed, S., & Leitner, W. (2015). Synergistic Interaction within Bifunctional Ruthenium Nanoparticle/SILP Catalysts for the Selective Hydrodeoxygenation of Phenols. Angewandte Chemie International Edition, 54(52), 15750-15755. doi:10.1002/anie.201508513.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002B-9AB5-E
Abstract
Ruthenium nanoparticles immobilized on acid-functionalized supported ionic liquid phases (Ru NPs@SILPs) act as efficient bifunctional catalysts in the hydrodeoxygenation of phenolic substrates under batch and continuous flow conditions. A synergistic interaction between the metal sites and acid groups within the bifunctional catalyst leads to enhanced catalytic activities for the overall transformation as compared to the individual steps catalyzed by the separate catalytic functionalities.