English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse
  1. View item / 
  2. Item Summary

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

Distance dependence of photoinduced electron-transfer: syntheses and properties of biphenylene-spacered porphyrin-quinone cyclophanes

MPS-Authors
/persons/resource/persons95446

Staab,  Heinz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

/persons/resource/persons93885

Kratzer,  Bernd
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

/persons/resource/persons199571

Quazzotti,  Serge
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

External Resource

http://onlinelibrary.wiley.com/doi/10.1002/(SICI)1099-0690(199810)1998:10%3C2149::AID-EJOC2149%3E3.0.CO;2-E/epdf
(Any fulltext)

Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Staab, H. A., Kratzer, B., & Quazzotti, S. (1998). Distance dependence of photoinduced electron-transfer: syntheses and properties of biphenylene-spacered porphyrin-quinone cyclophanes. European Journal of Organic Chemistry, 1998(10), 2149-2160. doi:10.1002/(SICI)1099-0690(199810)1998:10<2149:AID-EJOC2149>3.0.CO;2-E.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002B-A017-5
Abstract
In continuation of previous syntheses of benzene-, naphthalene-, and anthracene-spacered porphyrin-quinone cyclophanes 1, 2, and 4, biphenylene-spacered porphyrin-quinone cyclophanes of structure 3 as the “missing link” between 2 and 4 were prepared in multistep syntheses. These donor-acceptor systems are of interest since, with regard to electron-transfer rates, they complete the series of 1, 2, and 4. As expected the electron-transfer of 3 proceeds between that of 2 and 4 in an especially steep region of distance dependences of electron-transfer rates.