Higher Alcohol Synthesis Over Rh Catalysts: Conditioning of Rh/N-CNTs by Co and 
Mn Entrapped in the Support

Xie, Zailai; Frank, Benjamin; Huang, Xing; Schlögl, Robert; Trunschke, Annette

doi:10.1007/s10562-016-1875-6

Item

ITEM ACTIONSEXPORT

Add to Basket

Local TagsRelease HistoryDetailsSummary

Released

Journal Article

Higher Alcohol Synthesis Over Rh Catalysts: Conditioning of Rh/N-CNTs by Co and Mn Entrapped in the Support

MPS-Authors

/persons/resource/persons49294

Xie, Zailai
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;
College of Chemsitry, Fuzhou University, Qishan Campus;

/persons/resource/persons21519

Frank, Benjamin
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;
BasCat - UniCat BASF JointLab, Technische Universität Berlin, Sekr. EW K 01 ;

/persons/resource/persons39194

Huang, Xing
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22071

Schlögl, Robert
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22181

Trunschke, Annette
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

External Resource

No external resources are shared

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

Fulltext (public)

art_10.1007_s10562-016-1875-6.pdf
(Publisher version), 3MB

Supplementary Material (public)

There is no public supplementary material available

Citation

Xie, Z., Frank, B., Huang, X., Schlögl, R., & Trunschke, A. (2016). Higher Alcohol Synthesis Over Rh Catalysts: Conditioning of Rh/N-CNTs by Co and Mn Entrapped in the Support. Catalysis Letters, 146(12), 2417-2424. doi: 10.1007/s10562-016-1875-6.

Cite as: https://hdl.handle.net/11858/00-001M-0000-002C-03AE-0

Abstract

Rh nanoparticles supported on commercial non-purified N-doped CNTs (NCNTs) containing residual CNT growth catalyst have been studied in hydrogenation of CO to higher alcohols. It has been found that Co and Mn residues in NCNTs are not inert, but change the catalyst under reaction conditions and efficiently promote the catalyst resulting in both increasing activity and selectivity to C₂₊ alcohols with time on stream.