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Journal Article

[Hexane-2,5-dione bis­(thio­semi­carba­zon­ato)]nickel(II).

MPS-Authors
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Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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Fulltext (public)

2365692.pdf
(Publisher version), 318KB

Supplementary Material (public)

2365692_Suppl_1.cif
(Supplementary material), 18KB

2365692_Suppl_2.hkl
(Supplementary material), 152KB

Citation

Shalamzari, M. S., Gurbanov, A. V., Heidic, S., Kia, R., & Behrouzi, S. (2013). [Hexane-2,5-dione bis­(thio­semi­carba­zon­ato)]nickel(II). Acta Crystallographica Section E, 69(6): m322. doi:10.1107%2FS1600536813012816.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002C-01FE-0
Abstract
In the title compound, [Ni(C8H14N6S2)], the NiII ion is coordinated by N2S2 donor atoms of the tetradentate thio­semicarbazone ligand, and has a slightly distorted square-planar geometry. In the crystal, inversion-related mol­ecules are linked via pairs of N—H⋯N and N—H⋯S hydrogen bonds, forming R 2 2(8) ring motifs. Mol­ecules are further linked by slightly weaker N—H⋯N, N—H⋯S and C—H⋯S hydrogen bonds, forming two-dimensional networks which lie parallel to the bc plane.